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Issue 19, 2011
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Synthesis of ThCr2Si2-type arsenides from Bi flux

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Abstract

LaCo2As2 can be synthesized as pure crystalline material by annealing a mixture of elements in Bi flux. The reaction, however, is accompanied by the incorporation of a small quantity of Bi into the structure and the formation of vacancies in the Co sublattice, which lead to substantial changes in structural and magnetic properties of the material.

Graphical abstract: Synthesis of ThCr2Si2-type arsenides from Bi flux

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Publication details

The article was received on 29 Jan 2011, accepted on 11 Mar 2011 and first published on 11 Apr 2011


Article type: Communication
DOI: 10.1039/C1CC10578G
Citation: Chem. Commun., 2011,47, 5563-5565

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    Synthesis of ThCr2Si2-type arsenides from Bi flux

    C. M. Thompson, K. Kovnir, S. Eveland, M. J. Herring and M. Shatruk, Chem. Commun., 2011, 47, 5563
    DOI: 10.1039/C1CC10578G

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