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Issue 19, 2011
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Synthesis of ThCr2Si2-type arsenides from Bi flux

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Abstract

LaCo2As2 can be synthesized as pure crystalline material by annealing a mixture of elements in Bi flux. The reaction, however, is accompanied by the incorporation of a small quantity of Bi into the structure and the formation of vacancies in the Co sublattice, which lead to substantial changes in structural and magnetic properties of the material.

Graphical abstract: Synthesis of ThCr2Si2-type arsenides from Bi flux

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Article information


Submitted
29 Jan 2011
Accepted
11 Mar 2011
First published
11 Apr 2011

Chem. Commun., 2011,47, 5563-5565
Article type
Communication

Synthesis of ThCr2Si2-type arsenides from Bi flux

C. M. Thompson, K. Kovnir, S. Eveland, M. J. Herring and M. Shatruk, Chem. Commun., 2011, 47, 5563
DOI: 10.1039/C1CC10578G

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