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Issue 27, 2011
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Structure and magnetic ordering of a 2-D MnII(TCNE)I(OH2) (TCNE = tetracyanoethylene) organic-based magnet (Tc = 171 K)

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Abstract

MnII(TCNE)I(OH2) was isolated from the reaction of tetracyanoethylene (TCNE) and MnI2(THF)3, and has a 2-D structure possessing an unusual, asymmetric bonded μ4-[TCNE]˙. Direct antiferromagnetic coupling between the S = 5/2 MnII and S = 1/2 [TCNE]˙ leads to magnetic ordering as a canted antiferrimagnet at a Tc of 171 K.

Graphical abstract: Structure and magnetic ordering of a 2-D MnII(TCNE)I(OH2) (TCNE = tetracyanoethylene) organic-based magnet (Tc = 171 K)

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Article information


Submitted
24 Jan 2011
Accepted
03 Mar 2011
First published
20 Apr 2011

Chem. Commun., 2011,47, 7602-7604
Article type
Communication

Structure and magnetic ordering of a 2-D MnII(TCNE)I(OH2) (TCNE = tetracyanoethylene) organic-based magnet (Tc = 171 K)

S. H. Lapidus, A. C. McConnell, P. W. Stephens and J. S. Miller, Chem. Commun., 2011, 47, 7602
DOI: 10.1039/C1CC10478K

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