Issue 20, 2011
From the journal:

Chemical Communications

Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3†

Zachariah M. Heidena  and  Douglas W. Stephan*a  

* Corresponding authors

a Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada
E-mail: dstephan@chem.utoronto.ca

Abstract

Reductions of chiral ketimines effected under H2 by catalytic amounts of B(C6F5)3 result in moderate to excellent diastereoselectivities. In the case of camphor and menthone derived imines, the reductions proceeded with greater than 95% diastereoselectivity.

Graphical abstract: Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3

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Article information

DOI
https://doi.org/10.1039/C1CC10438A
Article type
Communication
Submitted
22 Jan 2011
Accepted
31 Mar 2011
First published
18 Apr 2011

Chem. Commun., 2011,47, 5729-5731

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Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3

Z. M. Heiden and D. W. Stephan, Chem. Commun., 2011, 47, 5729 DOI: 10.1039/C1CC10438A

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