Issue 18, 2011
From the journal:

Chemical Communications

Reversible single crystal to single crystal transformation with anion exchange-induced weak Cu2+⋯I− interactions and modification of the structures and properties of MOFs†

Junhong Fu,a   Huijun Li,a   Yajuan Mu,a   Hongwei Hou*a  and  Yaoting Fana  

* Corresponding authors

a Department of Chemistry, Zhengzhou University, Henan 450052, PR China
E-mail: houhongw@zzu.edu.cn
Fax: +86-371-67761744
Tel: +86-371-67761744

Abstract

{[Cu6(TTTMB)8(OH)4(H2O)6]·8(NO3)·34.5H2O}n can reversibly transform to {[Cu6(TTTMB)8I3]·9I·26H2O}n upon a single crystal to single crystal process. The transformation is accompanied by the formation of weak Cu2+⋯I− interactions and changes in the coordination numbers, as well as modulation in their properties.

Graphical abstract: Reversible single crystal to single crystal transformation with anion exchange-induced weak Cu2+⋯I− interactions and modification of the structures and properties of MOFs

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Article information

DOI
https://doi.org/10.1039/C1CC10251F
Article type
Communication
Submitted
14 Jan 2011
Accepted
17 Mar 2011
First published
31 Mar 2011

Chem. Commun., 2011,47, 5271-5273

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Reversible single crystal to single crystal transformation with anion exchange-induced weak Cu2+⋯I− interactions and modification of the structures and properties of MOFs

J. Fu, H. Li, Y. Mu, H. Hou and Y. Fan, Chem. Commun., 2011, 47, 5271 DOI: 10.1039/C1CC10251F

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