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Issue 15, 2011
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Phosphorescent self-assembled PtII tetranuclear metallocycles

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Abstract

A series of rigid Pt(II) diimine diacetylide complexes and their corresponding metallocyclic derivatives were synthesized through coordination-driven self-assembly. The photophysical properties of these complexes have been studied in detail, revealing exceptionally high RT phosphorescence quantum yields and lifetimes when the excited state becomes localized on the π-conjugated bridging-ligand following intramolecular charge-transfer sensitization.

Graphical abstract: Phosphorescent self-assembled PtII tetranuclear metallocycles

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Publication details

The article was received on 13 Jan 2011, accepted on 11 Feb 2011 and first published on 04 Mar 2011


Article type: Communication
DOI: 10.1039/C1CC10239G
Citation: Chem. Commun., 2011,47, 4397-4399

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    Phosphorescent self-assembled PtII tetranuclear metallocycles

    S. Goeb, V. Prusakova, X. Wang, A. Vézinat, M. Sallé and F. N. Castellano, Chem. Commun., 2011, 47, 4397
    DOI: 10.1039/C1CC10239G

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