Issue 12, 2011
From the journal:

Chemical Communications

Selective incorporation of functional dicarboxylates into zinc metal–organic frameworks†

Andrew D. Burrows,*a   Laura C. Fisher,ab   Christopher Richardsonac  and  Sean P. Rigbybd  

* Corresponding authors

a Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK
E-mail: a.d.burrows@bath.ac.uk
Fax: +44 (0)1225 386231
Tel: +44 (0)1225 386529

b Department of Chemical Engineering, University of Bath, Claverton Down, Bath BA2 7AY, UK

c School of Chemistry, University of Wollongong, Wollongong, Australia

d Department of Chemical and Environmental Engineering, University of Nottingham, University Park, Nottingham, UK

Abstract

Zinc(II) nitrate reacts with different ratios of 1,4-benzenedicarboxylic acid (H2bdc) and 2-halo-1,4-benzenedicarboxylic acid (H2bdc-X, X = Br or I) to give [Zn4O(bdc)3−x(bdc-X)x], in which preferential incorporation of bdc is observed. The selective incorporation is related to crystal growth rates, and the proportion of incorporated bdc-X rises with increasing reaction time.

Graphical abstract: Selective incorporation of functional dicarboxylates into zinc metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C1CC10143A
Article type
Communication
Submitted
07 Jan 2011
Accepted
31 Jan 2011
First published
15 Feb 2011

Chem. Commun., 2011,47, 3380-3382

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Selective incorporation of functional dicarboxylates into zinc metal–organic frameworks

A. D. Burrows, L. C. Fisher, C. Richardson and S. P. Rigby, Chem. Commun., 2011, 47, 3380 DOI: 10.1039/C1CC10143A

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