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Issue 12, 2011
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CO2 selectivity of a 1D microporous adenine-based metal–organic framework synthesised in water

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Abstract

The coordination of adenine to Ni2+ forms a dimer unit which can be linked by 3,5-pyrazoledicarboxylic acid into chains which assemble under hydrothermal conditions viahydrogen bonding into a robust porous network. The material displays selectivity for CO2 over CH4 and an isosteric heat which increases with guest loading.

Graphical abstract: CO2 selectivity of a 1D microporous adenine-based metal–organic framework synthesised in water

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Article information


Submitted
14 Dec 2010
Accepted
01 Feb 2011
First published
17 Feb 2011

Chem. Commun., 2011,47, 3389-3391
Article type
Communication

CO2 selectivity of a 1D microporous adenine-based metal–organic framework synthesised in water

K. C. Stylianou, J. E. Warren, S. Y. Chong, J. Rabone, J. Bacsa, D. Bradshaw and M. J. Rosseinsky, Chem. Commun., 2011, 47, 3389
DOI: 10.1039/C0CC05559J

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