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Issue 13, 2011

Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

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Abstract

Efficient catalysts for the dehydrocoupling or dehydropolymerisation of H3B·NMexH(3−x) (x = 1, 2) have been developed by variation of the P–Rh–P angle in {Rh(Ph2P(CH2)nPPh2)}+ fragments (n = 2–5).

Graphical abstract: Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

Supplementary files

Article information


Submitted
08 Dec 2010
Accepted
20 Jan 2011
First published
03 Feb 2011

Chem. Commun., 2011,47, 3763-3765
Article type
Communication

Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

R. Dallanegra, A. P. M. Robertson, A. B. Chaplin, I. Manners and A. S. Weller, Chem. Commun., 2011, 47, 3763 DOI: 10.1039/C0CC05460G

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