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Issue 11, 2011
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Unexpected preparation of (Z)-chloromethyleneketals and their sulfur analogues by a novel three-component condensation

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Abstract

A novel multicomponent condensation, leading to the rare (Z)-chloromethyleneketals and their sulfur analogues, has been discovered. The mechanism of this reaction has been studied in some detail and subsequent modifications were performed on the adducts, leading to unusual Umpolung transforms.

Graphical abstract: Unexpected preparation of (Z)-chloromethyleneketals and their sulfur analogues by a novel three-component condensation

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Publication details

The article was received on 25 Nov 2010, accepted on 10 Jan 2011 and first published on 01 Feb 2011


Article type: Communication
DOI: 10.1039/C0CC05186A
Chem. Commun., 2011,47, 3287-3289

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    Unexpected preparation of (Z)-chloromethyleneketals and their sulfur analogues by a novel three-component condensation

    F. Schevenels and I. E. Markó, Chem. Commun., 2011, 47, 3287
    DOI: 10.1039/C0CC05186A

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