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Issue 9, 2011
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Formation of chiral mesostructured porphyrin–silica hybrids

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Abstract

Formation of a chiral mesostructured porphyrinsilica hybrid with cylindrical helical stacking of anionic porphyrins was achieved by the aid of cationic organosilane. The enantiopurity of the hybrid was dramatically enhanced by a small amount of (R)-1,1′-bi-2-naphthol or its enantiomer.

Graphical abstract: Formation of chiral mesostructured porphyrin–silica hybrids

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Article information


Submitted
21 Nov 2010
Accepted
14 Dec 2010
First published
13 Jan 2011

Chem. Commun., 2011,47, 2607-2609
Article type
Communication

Formation of chiral mesostructured porphyrinsilica hybrids

H. Qiu, J. Xie and S. Che, Chem. Commun., 2011, 47, 2607
DOI: 10.1039/C0CC05078D

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