Issue 17, 2011
From the journal:

Chemical Communications

Bicyclic guanidinate compounds of magnesium and their activity as pre-catalysts in the Tishchenko reaction†

Benjamin M. Day,a   Natalie E. Mansfield,a   Martyn P. Coles*a  and  Peter B. Hitchcocka  

* Corresponding authors

a Department of Chemistry, University of Sussex, Falmer, Brighton BN1 9QJ, UK
E-mail: m.p.coles@sussex.ac.uk
Fax: +44 (0)1273 876687
Tel: +44 (0)1273 877339

Abstract

A synthetic route to magnesium guanidinate compounds that avoids ligand redistribution is reported; selected derivatives are active pre-catalysts in the dimerization of aldehydes.

Graphical abstract: Bicyclic guanidinate compounds of magnesium and their activity as pre-catalysts in the Tishchenko reaction

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Article information

DOI
https://doi.org/10.1039/C0CC04789A
Article type
Communication
Submitted
04 Nov 2010
Accepted
10 Mar 2011
First published
23 Mar 2011

Chem. Commun., 2011,47, 4995-4997

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Bicyclic guanidinate compounds of magnesium and their activity as pre-catalysts in the Tishchenko reaction

B. M. Day, N. E. Mansfield, M. P. Coles and P. B. Hitchcock, Chem. Commun., 2011, 47, 4995 DOI: 10.1039/C0CC04789A

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