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Issue 15, 2011
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A permanently porous van der Waals solid by using phosphonate monoester linkers in a metal organic framework

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Abstract

A bis(phosphonatemonoester) is employed as a linker in a Zn(II) metal organic framework. The complex is a layered structure pillared only by vdW interactions between alkyl groups. Nonetheless, permanent pores are formed as confirmed by PXRD and gas sorption analysis.

Graphical abstract: A permanently porous van der Waals solid by using phosphonate monoester linkers in a metal organic framework

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Publication details

The article was received on 04 Nov 2010, accepted on 04 Feb 2011 and first published on 09 Mar 2011


Article type: Communication
DOI: 10.1039/C0CC04779A
Chem. Commun., 2011,47, 4430-4432

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    A permanently porous van der Waals solid by using phosphonate monoester linkers in a metal organic framework

    S. S. Iremonger, J. Liang, R. Vaidhyanathan and G. K. H. Shimizu, Chem. Commun., 2011, 47, 4430
    DOI: 10.1039/C0CC04779A

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