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Issue 7, 2011
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Solid-to-solid formation at the solid–liquid interface leading to a chiral coordination polymer from an achiral monomer

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Abstract

An achiral crystal of a simple mononuclear copper complex [CuII(C6H8N2)2SO4]·H2O (1), on dipping into an aqueous azide solution, transforms into a chiral crystal of a coordination polymer [CuII(C6H8N2)(N3)2]n (2) in a solid–liquid interface reaction demonstrating replacement of a sulfate anion by an azide anion from an aqueous solution.

Graphical abstract: Solid-to-solid formation at the solid–liquid interface leading to a chiral coordination polymer from an achiral monomer

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Article information


Submitted
12 Oct 2010
Accepted
02 Dec 2010
First published
04 Jan 2011

Chem. Commun., 2011,47, 2062-2064
Article type
Communication

Solid-to-solid formation at the solid–liquid interface leading to a chiral coordination polymer from an achiral monomer

S. Supriya and S. K. Das, Chem. Commun., 2011, 47, 2062
DOI: 10.1039/C0CC04375C

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