Issue 1, 2011
From the journal:

Chemical Communications

A solid-state trimerisation of a diene diacid affords a bicyclobutyl: reactant structure from X-ray powder data and product separation and structure determination viaco-crystallisation†‡

Manza B. J. Atkinson,a   Ivan Halasz,b   Dejan-Krešimir Bučar,a   Robert E. Dinnebier,b   S. V. Santhana Mariappan,a   Anatoliy N. Sokolova  and  Leonard R. MacGillivray*a  

* Corresponding authors

a Department of Chemistry, University of Iowa, Iowa City, Iowa, USA
E-mail: len-macgillivray@uiowa.edu
Fax: +1 319-335-1270
Tel: +1 319-335-3504

b Max-Planck-Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart, Germany

Abstract

A bicyclobutyl that bears six carboxylic acid groups results from a trimerisation of a diene diacid in the solid state. Powder X-ray diffraction and a co-crystallisation are used to solve the structure of the diene and elucidate the stereochemistry of the bicyclobutyl, respectively.

Graphical abstract: A solid-state trimerisation of a diene diacid affords a bicyclobutyl: reactant structure from X-ray powder data and product separation and structure determination viaco-crystallisation

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Article information

DOI
https://doi.org/10.1039/C0CC02204G
Article type
Communication
Submitted
29 Jun 2010
Accepted
07 Aug 2010
First published
31 Aug 2010

Chem. Commun., 2011,47, 236-238

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A solid-state trimerisation of a diene diacid affords a bicyclobutyl: reactant structure from X-ray powder data and product separation and structure determination viaco-crystallisation

M. B. J. Atkinson, I. Halasz, D. Bučar, R. E. Dinnebier, S. V. Santhana Mariappan, A. N. Sokolov and L. R. MacGillivray, Chem. Commun., 2011, 47, 236 DOI: 10.1039/C0CC02204G

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