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Issue 1, 2011
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High-nuclearity, mixed-valence Mn17, Mn18 and {Mn62}n complexes from the use of triethanolamine

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Abstract

The use of both azide and triethanolamine, with or without the presence of carboxylate groups, has provided new Mn17, Mn18 and {Mn62}n complexes with aesthetically-pleasing cage, layered, and linked-chain-type structures; two are also new single-molecule magnets.

Graphical abstract: High-nuclearity, mixed-valence Mn17, Mn18 and {Mn62}n complexes from the use of triethanolamine

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Article information


Submitted
02 Jun 2010
Accepted
16 Jul 2010
First published
25 Aug 2010

Chem. Commun., 2011,47, 274-276
Article type
Communication

High-nuclearity, mixed-valence Mn17, Mn18 and {Mn62}n complexes from the use of triethanolamine

T. C. Stamatatos, D. Foguet-Albiol, W. Wernsdorfer, K. A. Abboud and G. Christou, Chem. Commun., 2011, 47, 274
DOI: 10.1039/C0CC01701A

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