Issue 47, 2010

Assembly of the Au–diphosphine helical cage molecules viaalkynyl–μ4-methylydine ligand transformation

Abstract

The assembly of the gold(I)diphosphine cages occurs via unprecedented transformation of the alkynyls into the μ4-methylydine ligands under basic conditions. These compounds demonstrate the equilibrium between the PM helical isomers and serve as hosts to accommodate small molecules (CH2Cl2 and CS2).

Graphical abstract: Assembly of the Au–diphosphine helical cage molecules via alkynyl–μ4-methylydine ligand transformation

Supplementary files

Article information

Article type
Communication
Submitted
18 Sep 2010
Accepted
13 Oct 2010
First published
01 Nov 2010

Chem. Commun., 2010,46, 8926-8928

Assembly of the Audiphosphine helical cage molecules via alkynylμ4-methylydine ligand transformation

I. O. Koshevoy, M. Haukka, S. I. Selivanov, S. P. Tunik and T. A. Pakkanen, Chem. Commun., 2010, 46, 8926 DOI: 10.1039/C0CC03953E

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