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Issue 45, 2010
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New insights into the acid mediated disproportionation of pentavalent uranyl

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Abstract

The reaction of benzoic acid with the uranyl(V) complex [(UO2Py5)(KI2Py2)] in pyridine leads to immediate disproportionation with formation of a hexanuclear U(IV) benzoate cluster, a bis-benzoate complex of uranyl(VI) and water.

Graphical abstract: New insights into the acid mediated disproportionation of pentavalent uranyl

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Publication details

The article was received on 24 Aug 2010, accepted on 01 Oct 2010 and first published on 18 Oct 2010


Article type: Communication
DOI: 10.1039/C0CC03443F
Citation: Chem. Commun., 2010,46, 8648-8650

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    New insights into the acid mediated disproportionation of pentavalent uranyl

    V. Mougel, B. Biswas, J. Pécaut and M. Mazzanti, Chem. Commun., 2010, 46, 8648
    DOI: 10.1039/C0CC03443F

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