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Issue 43, 2010
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Manganese(v)–oxocorroles in hydride-transfer reactions

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Abstract

Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues to manganese(V)–oxo corroles proceeds via proton-coupled electron transfer, followed by rapid electron transfer. The redox potentials (Ered) of manganese(V)–oxo corroles exhibit a good correlation with their reactivity in hydride-transfer reactions.

Graphical abstract: Manganese(v)–oxo corroles in hydride-transfer reactions

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Supplementary files

Article information


Submitted
20 Aug 2010
Accepted
20 Sep 2010
First published
11 Oct 2010

Chem. Commun., 2010,46, 8160-8162
Article type
Communication

Manganese(V)–oxo corroles in hydride-transfer reactions

Y. Han, Y. Lee, M. Mariappan, S. Fukuzumi and W. Nam, Chem. Commun., 2010, 46, 8160
DOI: 10.1039/C0CC03373A

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