Issue 42, 2010
From the journal:

Chemical Communications

Fabrication and transformation of novel two-dimensional tripod structures: structural modulation by alkyl chain length and tandem Claisen rearrangement†

Kazuhiro Omori,abc   Yoshihiro Kikkawa,*b   Masatoshi Kanesatob  and  Kazuhisa Hiratani*c  

* Corresponding authors

a Department of Materials Technology, Industrial Technology Center of Tochigi Prefecture, 367-1 Karinuma, Utsunomiya, Tochigi 321-3224, Japan

b Photonics Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8562, Japan
E-mail: y.kikkawa@aist.go.jp
Fax: +81-29-861-3029
Tel: +81-29-861-2955

c Department of Applied Chemistry, Utsunomiya University, 7-1-2 Youtou, Utsunomiya, Tochigi 321-8585, Japan
E-mail: hiratani@cc.utsunomiya-u.ac.jp
Fax: +81-28-689-6146
Tel: +81-28-689-6146

Abstract

Novel two-dimensional C3 symmetric (tripod) structures are fabricated from isobutenyl compounds possessing long alkyl chains. Alteration from tripod to wavy structures is accomplished by odd-even effect, and tandem Claisen rearrangement allows the transformation to the linear structures.

Graphical abstract: Fabrication and transformation of novel two-dimensional tripod structures: structural modulation by alkyl chain length and tandem Claisen rearrangement

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Article information

DOI
https://doi.org/10.1039/C0CC02963G
Article type
Communication
Submitted
02 Aug 2010
Accepted
07 Sep 2010
First published
27 Sep 2010

Chem. Commun., 2010,46, 8008-8010

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Fabrication and transformation of novel two-dimensional tripod structures: structural modulation by alkyl chain length and tandem Claisen rearrangement

K. Omori, Y. Kikkawa, M. Kanesato and K. Hiratani, Chem. Commun., 2010, 46, 8008 DOI: 10.1039/C0CC02963G

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