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Issue 42, 2010
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Chain mechanism for exchange of D2 with a ruthenium hydride

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Abstract

The ruthenium hydride of (Ar4CpOH)Ru(CO)2H exchanges cleanly and rapidly with D2 at room temperature to generate the ruthenium deuteride. A chain mechanism is proposed to explain the much more rapid exchange of RuH/D2 than RuCO exchange with 13CO.

Graphical abstract: Chain mechanism for exchange of D2 with a ruthenium hydride

  • This article is part of the themed collection: Hydrogen
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Publication details

The article was received on 28 Jul 2010, accepted on 01 Sep 2010 and first published on 21 Sep 2010


Article type: Communication
DOI: 10.1039/C0CC02875D
Citation: Chem. Commun., 2010,46, 7915-7917

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    Chain mechanism for exchange of D2 with a ruthenium hydride

    C. P. Casey, J. B. Johnson, X. Jiao, S. E. Beetner and S. W. Singer, Chem. Commun., 2010, 46, 7915
    DOI: 10.1039/C0CC02875D

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