Issue 42, 2010

13C NMR as a general tool for the assignment of absolute configuration

Abstract

13C NMR, alone or in combination with 1H NMR, allows the assignment of the absolute configuration of chiral alcohols, amines, carboxylic acids, thiols, cyanohydrins, sec,sec-diols and sec,sec-aminoalcohols, derivatized with appropriate chiral auxiliaries. This extends the assignment possibilities of NMR to fully deuterated and to nonproton containing compounds.

Graphical abstract: 13C NMR as a general tool for the assignment of absolute configuration

Supplementary files

Article information

Article type
Communication
Submitted
23 Jul 2010
Accepted
14 Sep 2010
First published
01 Oct 2010

Chem. Commun., 2010,46, 7903-7905

13C NMR as a general tool for the assignment of absolute configuration

I. Louzao, J. M. Seco, E. Quiñoá and R. Riguera, Chem. Commun., 2010, 46, 7903 DOI: 10.1039/C0CC02774J

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