Issue 45, 2010
From the journal:

Chemical Communications

Design and synthesis of a novel three-hindered quadrant bisphosphine ligand and its application in asymmetric hydrogenation†

Kexuan Huang,a   Xiaowei Zhang,ab   Thomas J. Emge,a   Guohua Hou,a   Bonan Caoa  and  Xumu Zhang*a  

* Corresponding authors

a Department of Chemistry and Chemical Biology & Department of Pharmaceutical Chemistry, Rutgers, The State University of New Jersey, Piscataway, USA
E-mail: xumu@rci.rutgers.edu
Fax: +1 732 445 6312
Tel: +1 732 445 1454

b Department of Chemistry, The Pennsylvania State University, University Park, USA

Abstract

A novel three hindered quadrant bisphosphine ligand has been synthesized. The ligand shows excellent enantioselectivities and reactivities for rhodium-catalyzed hydrogenations of various functionalized olefins.

Graphical abstract: Design and synthesis of a novel three-hindered quadrant bisphosphine ligand and its application in asymmetric hydrogenation

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Article information

DOI
https://doi.org/10.1039/C0CC02620D
Article type
Communication
Submitted
16 Jul 2010
Accepted
17 Aug 2010
First published
14 Oct 2010

Chem. Commun., 2010,46, 8555-8557

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Design and synthesis of a novel three-hindered quadrant bisphosphine ligand and its application in asymmetric hydrogenation

K. Huang, X. Zhang, T. J. Emge, G. Hou, B. Cao and X. Zhang, Chem. Commun., 2010, 46, 8555 DOI: 10.1039/C0CC02620D

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