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Issue 42, 2010
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Azulene based metal–organic frameworks for strong adsorption of H2

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Abstract

Two Zn MOFs, MOF-645 and MOF-646, comprised of polarized 1,3-azulenedicarboxylate were synthesized. The guest free MOF-646 showed strong MOF-H2 interactions (7.8–6.8 kJ mol−1), which revealed the significant impact of internally polarized azulene backbone to stabilized H2 molecules in the framework.

Graphical abstract: Azulene based metal–organic frameworks for strong adsorption of H2

  • This article is part of the themed collection: Hydrogen
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Article information


Submitted
15 Jul 2010
Accepted
03 Sep 2010
First published
27 Sep 2010

Chem. Commun., 2010,46, 7981-7983
Article type
Communication

Azulene based metal–organic frameworks for strong adsorption of H2

S. Barman, H. Furukawa, O. Blacque, K. Venkatesan, O. M. Yaghi and H. Berke, Chem. Commun., 2010, 46, 7981
DOI: 10.1039/C0CC02589E

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