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Issue 41, 2010
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Pd0-Catalyzed carbonylation of 1,1-dichloro-1-alkenes, a new selective access to Z-α-chloroacrylates

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Abstract

A novel and fully chemo- and stereoselective three component strategy leading to Z-α-chloroacrylates by a Pd0-catalyzed reaction of CO (1 atm) with 1,1-dichloro-1-alkenes and various alcohols is disclosed. This catalytic approach compares favourably with the Wittig type strategies as α-chloroacrylates of pure Z configuration are obtained in high yield.

Graphical abstract: Pd0-Catalyzed carbonylation of 1,1-dichloro-1-alkenes, a new selective access to Z-α-chloroacrylates

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Publication details

The article was received on 12 Jul 2010, accepted on 03 Sep 2010 and first published on 20 Sep 2010


Article type: Communication
DOI: 10.1039/C0CC02517H
Citation: Chem. Commun., 2010,46, 7810-7812

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    Pd0-Catalyzed carbonylation of 1,1-dichloro-1-alkenes, a new selective access to Z-α-chloroacrylates

    M. Arthuis, A. Lecup and E. Roulland, Chem. Commun., 2010, 46, 7810
    DOI: 10.1039/C0CC02517H

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