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Issue 36, 2010
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Sn[Si(SiMe3)3]3 and Sn3[Si(SiMe3)3]4: first insight into the mechanism of the disproportionation of a tin monohalide gives access to the shortest double bond of tin

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Abstract

In the course of the disproportionation reaction of a monohalide beside metalloid clusters like Sn10[Si(SiMe3)3]6 also molecular compounds with an average oxidation state of the tin atoms larger than one must be present. First results of such oxidized species are presented where the bonding is strongly influenced by the steric bulk of the ligands leading to the shortest tintin double bond.

Graphical abstract: Sn[Si(SiMe3)3]3− and Sn3[Si(SiMe3)3]4: first insight into the mechanism of the disproportionation of a tin monohalide gives access to the shortest double bond of tin

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Publication details

The article was received on 05 Jul 2010, accepted on 23 Jul 2010 and first published on 18 Aug 2010


Article type: Communication
DOI: 10.1039/C0CC02367A
Chem. Commun., 2010,46, 6756-6758

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    Sn[Si(SiMe3)3]3 and Sn3[Si(SiMe3)3]4: first insight into the mechanism of the disproportionation of a tin monohalide gives access to the shortest double bond of tin

    C. Schrenk and A. Schnepf, Chem. Commun., 2010, 46, 6756
    DOI: 10.1039/C0CC02367A

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