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Issue 36, 2010
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Remote amide-directed palladium-catalyzed benzylic C–H amination with N-fluorobenzenesulfonimide

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Abstract

An unprecedented remote amide-directed palladium-catalyzed intermolecular highly selective benzylic C–H amination with N-fluorobenzenesulfonimide is developed, which represents the first direct benzylic C–H amination with a non-nitrene nitrogen source. This methodology provides a novel approach to circumvent the common ortho aromatic C–H selectivity in directed palladium catalyzed C–H functionalization.

Graphical abstract: Remote amide-directed palladium-catalyzed benzylic C–H amination with N-fluorobenzenesulfonimide

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Supplementary files

Article information


Submitted
29 Jun 2010
Accepted
26 Jul 2010
First published
18 Aug 2010

Chem. Commun., 2010,46, 6831-6833
Article type
Communication

Remote amide-directed palladium-catalyzed benzylic C–H amination with N-fluorobenzenesulfonimide

T. Xiong, Y. Li, Y. Lv and Q. Zhang, Chem. Commun., 2010, 46, 6831
DOI: 10.1039/C0CC02175J

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