Issue 40, 2010

Selective α-defluorination of polyfluorinated esters and amides using SmI2/Et3N/H2O

Abstract

SmI2/H2O promotes selective α-monodefluorinations, while addition of an amine results in complete α-defluorination reactions.

Graphical abstract: Selective α-defluorination of polyfluorinated esters and amides using SmI2/Et3N/H2O

Supplementary files

Article information

Article type
Communication
Submitted
22 Jun 2010
Accepted
12 Aug 2010
First published
14 Sep 2010

Chem. Commun., 2010,46, 7596-7598

Selective α-defluorination of polyfluorinated esters and amides using SmI2/Et3N/H2O

J. Wettergren, T. Ankner and G. Hilmersson, Chem. Commun., 2010, 46, 7596 DOI: 10.1039/C0CC02009E

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