Issue 36, 2010

Organocatalytic asymmetric Michael addition of α-aryl cyclopentanones to nitroolefins for construction of adjacent quaternary and tertiary stereocenters

Abstract

The first asymmetric Michael addition of α-aryl cyclopentanones to nitroolefins for construction of adjacent quaternary and tertiary stereocenters has been achieved with excellent diastereo-/enantioselectivity.

Graphical abstract: Organocatalytic asymmetric Michael addition of α-aryl cyclopentanones to nitroolefins for construction of adjacent quaternary and tertiary stereocenters

Supplementary files

Article information

Article type
Communication
Submitted
21 Jun 2010
Accepted
16 Jul 2010
First published
20 Aug 2010

Chem. Commun., 2010,46, 6840-6842

Organocatalytic asymmetric Michael addition of α-aryl cyclopentanones to nitroolefins for construction of adjacent quaternary and tertiary stereocenters

X. Dong, H. Teng, M. Tong, H. Huang, H. Tao and C. Wang, Chem. Commun., 2010, 46, 6840 DOI: 10.1039/C0CC01987A

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