Issue 35, 2010

Effect of hydrophobic interaction cooperating with double Lewis acid activation in a zinc(ii) phosphodiesterase mimic

Abstract

The novel dinuclear Zn(II) complex (1) containing a β-CD dimer could accelerate BNPP (a DNA substitute) hydrolysis more efficiently than catalyze HPNP (a RNA substitute) transesterification with different mechanisms involved; the β-CDs played remarkably different roles.

Graphical abstract: Effect of hydrophobic interaction cooperating with double Lewis acid activation in a zinc(ii) phosphodiesterase mimic

Supplementary files

Article information

Article type
Communication
Submitted
09 Apr 2010
Accepted
15 Jul 2010
First published
09 Aug 2010

Chem. Commun., 2010,46, 6497-6499

Effect of hydrophobic interaction cooperating with double Lewis acid activation in a zinc(II) phosphodiesterase mimic

M. Zhao, L. Zhang, H. Chen, H. Wang, L. Ji and Z. Mao, Chem. Commun., 2010, 46, 6497 DOI: 10.1039/C0CC00838A

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