Issue 36, 2010
From the journal:

Chemical Communications

Induction of axially chiral N–C bonds in N-aryl acridane and related complexes by chromium tricarbonyl migration reactions†

Akiyoshi Mori,a   Shunsuke Kinoshita,a   Masaru Furusyob  and  Ken Kamikawa*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka Prefecture University Sakai, Osaka 599-8531, Japan
E-mail: kamikawa@c.s.osakafu-u.ac.jp
Fax: +81 72-254-9931
Tel: +81 72-254-9721

b Analysis Technology Research Center, Sumitomo Electric Industries Ltd., 1-1-1, Koyakita, Itami, Hyogo, Japan

Abstract

The thermal chromium tricarbonyl migration reaction induced axially chiral N–C bonds of N-aryl acridane and related complexes in good yield with outstanding enantiomeric excess.

Graphical abstract: Induction of axially chiral N–C bonds in N-aryl acridane and related complexes by chromium tricarbonyl migration reactions

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Article information

DOI
https://doi.org/10.1039/C0CC00836B
Article type
Communication
Submitted
09 Apr 2010
Accepted
30 Jul 2010
First published
20 Aug 2010

Chem. Commun., 2010,46, 6846-6848

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Induction of axially chiral N–C bonds in N-aryl acridane and related complexes by chromium tricarbonyl migration reactions

A. Mori, S. Kinoshita, M. Furusyo and K. Kamikawa, Chem. Commun., 2010, 46, 6846 DOI: 10.1039/C0CC00836B

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