Issue 31, 2010
From the journal:

Chemical Communications

Enhanced electrogenerated chemiluminescence of a ruthenium tris(2,2′)bipyridyl/tripropylamine system on a boron-doped diamond nanograss array†

Yongtak Yang,a   Jeong-Wook Oh,a   Yang-Rae Kim,a   Chiaki Terashima,b   Akira Fujishima,c   Jong Seung Kim*d  and  Hasuck Kim*a  

* Corresponding authors

a Department of Chemistry, Seoul National University, Seoul 151-747, Korea
E-mail: hasuckim@snu.ac.kr

b Technology Research and Development Department, General Technology Division, Central Japan Railway, 1545-33 Ohyama, Komaki City, Aichi 485-0801, Japan

c Kanagawa Academy of Science and Technology, KSP, 3-2-1 Sakado, Kawasaki 213-0012, Japan

d Department of Chemistry, Korea University, Seoul 136-701, Korea
E-mail: jongskim@korea.ac.kr

Abstract

Significant enhancement of the ECL signals from the Ru(bpy)32+/TPA system was achieved when using a BDD nanograss array, mainly because of the highly facile oxidation of TPA. The facile oxidation of TPA is due to the superior properties of the BDD nanograss array, such as improved electrocatalytic activity and accelerated electron transfer.

Graphical abstract: Enhanced electrogenerated chemiluminescence of a ruthenium tris(2,2′)bipyridyl/tripropylamine system on a boron-doped diamond nanograss array

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Article information

DOI
https://doi.org/10.1039/C0CC00773K
Article type
Communication
Submitted
05 Apr 2010
Accepted
26 May 2010
First published
28 Jun 2010

Chem. Commun., 2010,46, 5793-5795

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Enhanced electrogenerated chemiluminescence of a ruthenium tris(2,2′)bipyridyl/tripropylamine system on a boron-doped diamond nanograss array

Y. Yang, J. Oh, Y. Kim, C. Terashima, A. Fujishima, J. S. Kim and H. Kim, Chem. Commun., 2010, 46, 5793 DOI: 10.1039/C0CC00773K

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