Issue 29, 2010
From the journal:

Chemical Communications

Rational design of efficient rhodiumcatalysts for the anti-markovnikov oxidative amination of styrene†

M. Victoria Jiménez,*a   Jesús J. Pérez-Torrente,*a   M. Isabel Bartolomé,a   Fernando J. Lahoza  and  Luis A. Oroa  

* Corresponding authors

a Departamento de Química Inorgánica, Instituto Universitario de Catálisis Homogénea, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-C.S.I.C., 50009-Zaragoza, Spain
E-mail: vjimenez@unizar.es, perez@unizar.es
Fax: +34 976 761187
Tel: +34 976 762286

Abstract

Cationic rhodium(I) complexes containing the flexible hemilabile phosphine ligand (3-ethoxypropyl)diphenylphosphine efficiently catalyzed the anti-Markovnikov oxidative amination of styrene in tetrahydrofurane at 80 °C to produce (E)-1-styrylpiperidine with turnover frequencies up to 75 h−1 with excellent enamine selectivity (96%).

Graphical abstract: Rational design of efficient rhodium catalysts for the anti-markovnikov oxidative amination of styrene

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Article information

DOI
https://doi.org/10.1039/C0CC00525H
Article type
Communication
Submitted
22 Mar 2010
Accepted
25 May 2010
First published
24 Jun 2010

Chem. Commun., 2010,46, 5322-5324

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Rational design of efficient rhodium catalysts for the anti-markovnikov oxidative amination of styrene

M. V. Jiménez, J. J. Pérez-Torrente, M. I. Bartolomé, F. J. Lahoz and L. A. Oro, Chem. Commun., 2010, 46, 5322 DOI: 10.1039/C0CC00525H

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