Issue 22, 2010
From the journal:

Chemical Communications

Self-assembly from metal–organic vesicles to globular networks: metallogel-mediated phenylation of indole with phenyl boronic acid†

Li Yang,a   Liang Luo,a   Shuai Zhang,a   Xiaoyu Su,a   Jingbo Lan,a   Chi-Tien Chenb  and  Jingsong You*a  

* Corresponding authors

a Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Hospital, Sichuan University, Chengdu 610064, People’s Republic of China
E-mail: jsyou@scu.edu.cn

b Department of Chemistry, National Chung Hsing University, Taichung 402, Taiwan

Abstract

Self-assembly of the conformationally flexible bismethylimidazolyl ligands with Pd(OAc)2 is described. Depending on whether the ligands provide the hydrogen bonding donor, a switching of metal–organic vesicles to globular networks gelating solvents is achieved. The metallogels exhibit catalytic activity for the cross-coupling of indole with phenyl boronic acid.

Graphical abstract: Self-assembly from metal–organic vesicles to globular networks: metallogel-mediated phenylation of indole with phenyl boronic acid

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Article information

DOI
https://doi.org/10.1039/C0CC00112K
Article type
Communication
Submitted
25 Feb 2010
Accepted
12 Apr 2010
First published
27 Apr 2010

Chem. Commun., 2010,46, 3938-3940

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Self-assembly from metal–organic vesicles to globular networks: metallogel-mediated phenylation of indole with phenyl boronic acid

L. Yang, L. Luo, S. Zhang, X. Su, J. Lan, C. Chen and J. You, Chem. Commun., 2010, 46, 3938 DOI: 10.1039/C0CC00112K

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