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Issue 18, 2010
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Amino-borane oligomers bound to a Rh(I) metal fragment

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Coordination complexes of previously observed intermediates, H3B·NMe2BH2·NMe2H and [H2BNMeH]3, in the transition metal catalysed dehydrocoupling of H3B·NMe2H and H3B·NMeH2 have been isolated and structurally characterised using the [Rh{PR′22-C5H7)}]+ fragment. Their onward reactivity shows that further dehydrogenation is not a simple intramolecular process.

Graphical abstract: Amino-borane oligomers bound to a Rh(i) metal fragment

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The article was received on 12 Feb 2010, accepted on 04 Mar 2010 and first published on 23 Mar 2010

Article type: Communication
DOI: 10.1039/C003055D
Chem. Commun., 2010,46, 3092-3094

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    Amino-borane oligomers bound to a Rh(I) metal fragment

    R. Dallanegra, A. B. Chaplin, J. Tsim and A. S. Weller, Chem. Commun., 2010, 46, 3092
    DOI: 10.1039/C003055D

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