Issue 18, 2010
From the journal:

Chemical Communications

Amino-borane oligomers bound to a Rh(i) metal fragment†

Romaeo Dallanegra,a   Adrian B. Chaplin,a   Jennifer Tsima  and  Andrew S. Weller*a  

* Corresponding authors

a Department of Chemistry, Inorganic Chemistry Laboratory, University of Oxford, Oxford, UK
E-mail: andrew.weller@chem.ox.ac.uk
Tel: +44 (0)1865 285151

Abstract

Coordination complexes of previously observed intermediates, H3B·NMe2BH2·NMe2H and [H2BNMeH]3, in the transition metal catalysed dehydrocoupling of H3B·NMe2H and H3B·NMeH2 have been isolated and structurally characterised using the [Rh{PR′2(η2-C5H7)}]+ fragment. Their onward reactivity shows that further dehydrogenation is not a simple intramolecular process.

Graphical abstract: Amino-borane oligomers bound to a Rh(i) metal fragment

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Article information

DOI
https://doi.org/10.1039/C003055D
Article type
Communication
Submitted
12 Feb 2010
Accepted
04 Mar 2010
First published
23 Mar 2010

Chem. Commun., 2010,46, 3092-3094

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Amino-borane oligomers bound to a Rh(I) metal fragment

R. Dallanegra, A. B. Chaplin, J. Tsim and A. S. Weller, Chem. Commun., 2010, 46, 3092 DOI: 10.1039/C003055D

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