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Issue 23, 2010
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Synthesis of reaction-ready 6,6′-biindole and 6,6′-biisatinviapalladium(ii)-catalysed intramolecular C–H functionalisation

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Abstract

The first synthesis of a 6,6′-biindole and 6,6′-biisatin scaffold is reported with the penultimate step being the formation of the di-heterocyclic ring by Pd(II)-catalysed intramolecular C–H functionalisation and Sandmeyer cyclisation, respectively.

Graphical abstract: Synthesis of reaction-ready 6,6′-biindole and 6,6′-biisatin via palladium(ii)-catalysed intramolecular C–H functionalisation

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Supplementary files

Article information


Submitted
01 Feb 2010
Accepted
04 Mar 2010
First published
23 Mar 2010

Chem. Commun., 2010,46, 4076-4078
Article type
Communication

Synthesis of reaction-ready 6,6′-biindole and 6,6′-biisatin via palladium(II)-catalysed intramolecular C–H functionalisation

A. B. Gamble and P. A. Keller, Chem. Commun., 2010, 46, 4076 DOI: 10.1039/C002098B

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