Issue 19, 2010
From the journal:

Chemical Communications

Aryl-bromide reductive elimination from an isolated Pt(iv) complex†

Anette Yahav-Levi,a   Israel Goldberg,a   Arkadi Vigalok*a  and  Andrei N. Vedernikov*b  

* Corresponding authors

a School of Chemistry, The Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv 69978, Israel
E-mail: avigal@post.tau.ac.il
Fax: +972-3-6409293
Tel: +972-3-6408617

b Department of Chemistry and Biochemistry, University of Maryland, College Park, USA
E-mail: avederni@umd.edu
Tel: +1-301-405-2784

Abstract

A Pt(IV) complex bearing two aryl and two bromo ligands, which undergoes selective elimination of a bromoarene molecule has been prepared and fully-characterized. The mechanistic studies of this reaction are presented.

Graphical abstract: Aryl-bromide reductive elimination from an isolated Pt(iv) complex

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Article information

DOI
https://doi.org/10.1039/C001487G
Article type
Communication
Submitted
22 Jan 2010
Accepted
09 Apr 2010
First published
16 Apr 2010

Chem. Commun., 2010,46, 3324-3326

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Aryl-bromide reductive elimination from an isolated Pt(IV) complex

A. Yahav-Levi, I. Goldberg, A. Vigalok and A. N. Vedernikov, Chem. Commun., 2010, 46, 3324 DOI: 10.1039/C001487G

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