Issue 13, 2010
From the journal:

Chemical Communications

High chemo and regioselective formation of alcohols from the hydrocarbonylation of alkenes using cooperative ligand effects†

Inẽ I. F. Boogaerts,a   Daniel F. S. Whiteb  and  David J. Cole-Hamilton*a  

* Corresponding authors

a EaStCHEM, School of Chemistry, University of St. Andrews, St. Andrews, Fife, Scotland, UK
E-mail: djc@st-and.ac.uk
Fax: +44 (0)1334 463808
Tel: +44 (0)1334 463808

b Lyondell Chemical Company, 3801 West Chester Pike, Newtown Square, USA
E-mail: Daniel.White@lyondellbasell.com
Fax: +1-610-359-4866
Tel: +1-610-359-2064

Abstract

The hydrocarbonylation of alkenes, including allyl alcohol, catalysed by rhodium complexes and wide angle bidentate ligands together with PEt3, gives alcohols as the primary products with high chemo and regio-selectivity.

Graphical abstract: High chemo and regioselective formation of alcohols from the hydrocarbonylation of alkenes using cooperative ligand effects

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Article information

DOI
https://doi.org/10.1039/B927236D
Article type
Communication
Submitted
23 Dec 2009
Accepted
10 Feb 2010
First published
26 Feb 2010

Chem. Commun., 2010,46, 2194-2196

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High chemo and regioselective formation of alcohols from the hydrocarbonylation of alkenes using cooperative ligand effects

I. I. F. Boogaerts, D. F. S. White and D. J. Cole-Hamilton, Chem. Commun., 2010, 46, 2194 DOI: 10.1039/B927236D

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