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Issue 11, 2010
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α-Functionalization of non-activated aliphatic amines: ruthenium-catalyzed alkynylations and alkylations

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Abstract

Novel catalytic α-functionalizations of non-activated aliphatic amines with silylated alkynes are reported. In the presence of the Shvo catalyst alkylations and alkynylations proceed highly selectively to the branched amines.

Graphical abstract: α-Functionalization of non-activated aliphatic amines: ruthenium-catalyzed alkynylations and alkylations

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Publication details

The article was received on 24 Nov 2009, accepted on 22 Dec 2009 and first published on 14 Jan 2010


Article type: Communication
DOI: 10.1039/B924674F
Citation: Chem. Commun., 2010,46, 1956-1958

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    α-Functionalization of non-activated aliphatic amines: ruthenium-catalyzed alkynylations and alkylations

    I. Jovel, S. Prateeptongkum, R. Jackstell, N. Vogl, C. Weckbecker and M. Beller, Chem. Commun., 2010, 46, 1956
    DOI: 10.1039/B924674F

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