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Issue 15, 2010
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Axial ligand control over monolayer and bilayer formation of metal-salophens at the liquid–solid interface

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Abstract

Nickel salophens exclusively form monolayers at a liquid–solid interface, while in contrast zinc salophens mainly self-assemble into bilayers via axial ligand self-coordination which can be disrupted by the addition of pyridine axial ligands.

Graphical abstract: Axial ligand control over monolayer and bilayer formation of metal-salophens at the liquid–solid interface

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Submitted
23 Oct 2009
Accepted
07 Jan 2010
First published
25 Jan 2010

Chem. Commun., 2010,46, 2548-2550
Article type
Communication

Axial ligand control over monolayer and bilayer formation of metal-salophens at the liquid–solid interface

J. A. A. W. Elemans, S. J. Wezenberg, M. J. J. Coenen, E. C. Escudero-Adán, J. Benet-Buchholz, D. den Boer, S. Speller, A. W. Kleij and S. De Feyter, Chem. Commun., 2010, 46, 2548
DOI: 10.1039/B922212J

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