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Issue 6, 2010
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Nitrones as dipoles for rapid strain-promoted 1,3-dipolar cycloadditions with cyclooctynes

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Abstract

Strain-promoted cycloadditions of nitrones with cyclooctynes (k2 = 1.5 M−1 s−1 at 25 °C) are up to 25 times more rapid than comparable reactions of azides.

Graphical abstract: Nitrones as dipoles for rapid strain-promoted 1,3-dipolar cycloadditions with cyclooctynes

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Article information


Submitted
15 Oct 2009
Accepted
08 Dec 2009
First published
23 Dec 2009

Chem. Commun., 2010,46, 931-933
Article type
Communication

Nitrones as dipoles for rapid strain-promoted 1,3-dipolar cycloadditions with cyclooctynes

C. S. McKay, J. Moran and J. P. Pezacki, Chem. Commun., 2010, 46, 931
DOI: 10.1039/B921630H

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