Issue 6, 2010
From the journal:

Chemical Communications

Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes†‡

Azusa Kondoha  and  Timothy F. Jamison*a  

* Corresponding authors

a Massachusetts Institute of Technology, Department of Chemistry, Cambridge, Massachusetts 02139, USA
E-mail: tfj@mit.edu
Fax: +1 617 324 0253
Tel: +1 617 253 2135

Abstract

A rhodium-catalyzed dehydrogenative borylation of cyclic alkenes is described. This reaction provides direct access to cyclic 1-alkenylboronic acid pinacol esters, useful intermediates in organic synthesis. Suzuki–Miyaura cross-coupling applications are also presented.

Graphical abstract: Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes

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Article information

DOI
https://doi.org/10.1039/B921387B
Article type
Communication
Submitted
14 Oct 2009
Accepted
10 Dec 2009
First published
05 Jan 2010

Chem. Commun., 2010,46, 907-909

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Rhodium-catalyzed dehydrogenative borylation of cyclic alkenes

A. Kondoh and T. F. Jamison, Chem. Commun., 2010, 46, 907 DOI: 10.1039/B921387B

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