Issue 8, 2010
From the journal:

Chemical Communications

The first example of metallocene-like coordination mode of THBQ4−: A mixed-valence heptanucler palladium complex [Pd7(THBQ)2(tben)6](PF6)4†

Eiji Asato,*a   Ayano Kyan,a   Tomokura Madanbashi,a   Toshihide Tamura,a   Makoto Tadokorob  and  Motohiro Mizunoc  

* Corresponding authors

a Department of Chemistry, Biology and Marine Science, Faculty of Science, University of the Ryukyus, Nishihara, Okinawa 903-0213, Japan
E-mail: asato@sci.u-ryukyu.ac.jp

b Department of Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka 1-3, Shinjuku-ku, Tokyo 162-8601, Japan

c Department of Chemistry, Faculty of Science, Kanazawa University, Kanazawa 920-1192, Japan

Abstract

The title compound adopts a structure reminiscent of metallocene analogues, in which two disk-like units [PdII3(THBQ)(tben)3]2+ bind to one naked Pd0 metal in a sandwich form through each C6O64− (THBQ4−) ring with an η6-binding fashion.

Graphical abstract: The first example of metallocene-like coordination mode of THBQ4−: A mixed-valence heptanucler palladium complex [Pd7(THBQ)2(tben)6](PF6)4

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Article information

DOI
https://doi.org/10.1039/B919854G
Article type
Communication
Submitted
23 Sep 2009
Accepted
11 Dec 2009
First published
12 Jan 2010

Chem. Commun., 2010,46, 1227-1228

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The first example of metallocene-like coordination mode of THBQ4−: A mixed-valence heptanucler palladium complex [Pd7(THBQ)2(tben)6](PF6)4

E. Asato, A. Kyan, T. Madanbashi, T. Tamura, M. Tadokoro and M. Mizuno, Chem. Commun., 2010, 46, 1227 DOI: 10.1039/B919854G

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