Issue 6, 2010
From the journal:

Chemical Communications

Reversible complexation of isocyanides by the distannyneAr′SnSnAr′ (Ar′ = C6H3-2,6(C6H3-2,6-iPr2)2)†

Yang Peng,a   Xinping Wang,a   James C. Fettingera  and  Philip P. Power*a  

* Corresponding authors

a Department of Chemistry, University of California, Davis, USA
E-mail: pppower@ucdavis.edu
Fax: +1-530-752-8995
Tel: +1-530-752-6913

Abstract

The reaction of the distannyne Ar′SnSnAr′ (Ar′ = C6H3-2,6(C6H3-2,6-iPr2)2) with tert-butyl or mesityl isocyanide afforded the bis-adducts Ar′SnSnAr′(CNBut)2 or Ar′SnSnAr′ (CNMes)2 in which the isonitriles are reversibly bound under ambient conditions.

Graphical abstract: Reversible complexation of isocyanides by the distannyne Ar′SnSnAr′ (Ar′ = C6H3-2,6(C6H3-2,6-iPr2)2)

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Article information

DOI
https://doi.org/10.1039/B919828H
Article type
Communication
Submitted
23 Sep 2009
Accepted
07 Dec 2009
First published
08 Jan 2010

Chem. Commun., 2010,46, 943-945

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Reversible complexation of isocyanides by the distannyne Ar′SnSnAr′ (Ar′ = C6H3-2,6(C6H3-2,6-iPr2)2)

Y. Peng, X. Wang, J. C. Fettinger and P. P. Power, Chem. Commun., 2010, 46, 943 DOI: 10.1039/B919828H

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