Issue 1, 2010

Formation of tetrameric waterclusters driven by a cavitand template

Abstract

We describe an innovative approach to the generation of tetrameric water clusters in the solid state. The specific H-bond pattern induced by the tetraphosphonate cavitand template via its rigidly preorganized P[double bond, length as m-dash]O acceptor groups leads to the exclusive formation of the unique cyclic homodromic water tetramer of C4 symmetry.

Graphical abstract: Formation of tetrameric water clusters driven by a cavitand template

Supplementary files

Article information

Article type
Communication
Submitted
02 Sep 2009
Accepted
08 Oct 2009
First published
26 Oct 2009

Chem. Commun., 2010,46, 88-90

Formation of tetrameric water clusters driven by a cavitand template

C. Massera, M. Melegari, F. Ugozzoli and E. Dalcanale, Chem. Commun., 2010, 46, 88 DOI: 10.1039/B917931C

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