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Issue 9, 2010
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Local structural properties of 0.5BiMnO3–0.5ATiO3 (A = Ba or Sr)

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Abstract

Neutron total scattering data have been used to probe the long- and short-range structure of 0.5BiMnO3–0.5ATiO3 (A = Ba or Sr). Modelling of the total scattering data, using the reverse Monte Carlo (RMC) method, reveals local disorder that differs substantially from the average structure. Significantly, the Bi3+ cations prefer to adopt an asymmetric coordination due to the influence of the lone-pair electrons.

Graphical abstract: Local structural properties of 0.5BiMnO3–0.5ATiO3 (A = Ba or Sr)

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Article information


Submitted
25 Jun 2009
Accepted
15 Dec 2009
First published
14 Jan 2010

Chem. Commun., 2010,46, 1455-1457
Article type
Communication

Local structural properties of 0.5BiMnO3–0.5ATiO3 (A = Ba or Sr)

S. T. Norberg, S. Hull, R. Mathieu and S. G. Eriksson, Chem. Commun., 2010, 46, 1455 DOI: 10.1039/B912519A

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