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A molecule capable of both autocatalysis and organocatalysis was synthesized. The autocatalytic activity results from the self-complementary recognition sites provided by hydrogen bonding between heterocyclic subunits and the organocatalysis resides in an embedded thiourea function. The behavior of the molecule suggests both replication and metabolism can be engineered into synthetic compounds.
S. Kamioka, D. Ajami and J. Rebek Jr., Chem. Commun., 2009, 7324 DOI: 10.1039/B916836B
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