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Issue 43, 2009
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Catalytic enantioselective boron conjugate addition to cyclic carbonyl compounds: a new approach to cyclic β-hydroxy carbonyls

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Abstract

The highly enantioselective conjugate boration of six-membered and seven-membered cyclic enones and unsaturated esters was achieved by the use of a copper–(R,S)-Taniaphos complex with up to 99% ee under optimal conditions.

Graphical abstract: Catalytic enantioselective boron conjugate addition to cyclic carbonyl compounds: a new approach to cyclic β-hydroxy carbonyls

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Publication details

The article was received on 15 Jul 2009, accepted on 02 Sep 2009 and first published on 17 Sep 2009


Article type: Communication
DOI: 10.1039/B914207J
Chem. Commun., 2009, 6577-6579

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    Catalytic enantioselective boron conjugate addition to cyclic carbonyl compounds: a new approach to cyclic β-hydroxy carbonyls

    X. Feng and J. Yun, Chem. Commun., 2009, 6577
    DOI: 10.1039/B914207J

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