Issue 43, 2009

Catalytic enantioselective boron conjugate addition to cyclic carbonyl compounds: a new approach to cyclic β-hydroxy carbonyls

Abstract

The highly enantioselective conjugate boration of six-membered and seven-membered cyclic enones and unsaturated esters was achieved by the use of a copper–(R,S)-Taniaphos complex with up to 99% ee under optimal conditions.

Graphical abstract: Catalytic enantioselective boron conjugate addition to cyclic carbonyl compounds: a new approach to cyclic β-hydroxy carbonyls

Supplementary files

Article information

Article type
Communication
Submitted
15 Jul 2009
Accepted
02 Sep 2009
First published
17 Sep 2009

Chem. Commun., 2009, 6577-6579

Catalytic enantioselective boron conjugate addition to cyclic carbonyl compounds: a new approach to cyclic β-hydroxy carbonyls

X. Feng and J. Yun, Chem. Commun., 2009, 6577 DOI: 10.1039/B914207J

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