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Issue 41, 2009
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Amide-based bifunctional organocatalysts in asymmetric reactions

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Abstract

A series of amide-based bifunctional organocatalysts have been utilized in asymmetric reactions. Prolinamide analogues have been designed to catalyze asymmetric reactions via enamine intermediates with the assistance of tunable hydrogen bonding. In addition, the combination of various Lewis base functional groups, such as guanidine, N-oxide and phosphane, with an amide moiety have also constituted efficient bifunctional organocatalysts with unique reactivity and selectivity.

Graphical abstract: Amide-based bifunctional organocatalysts in asymmetric reactions

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Publication details

The article was received on 06 Jul 2009, accepted on 11 Aug 2009 and first published on 27 Aug 2009


Article type: Feature Article
DOI: 10.1039/B913411E
Chem. Commun., 2009, 6145-6158

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    Amide-based bifunctional organocatalysts in asymmetric reactions

    X. Liu, L. Lin and X. Feng, Chem. Commun., 2009, 6145
    DOI: 10.1039/B913411E

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