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Issue 38, 2009
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Dual reactivity of a photochemically-generated cyclic enyne–allene

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Abstract

A reactive ten-membered ring enyne–allene (τ25 °C = 5–6 min) is efficiently generated (Φ300 nm = 0.57) by UV irradiation of a thermally stable precursor in which a triple bond is masked as a cyclopropenone moiety.

Graphical abstract: Dual reactivity of a photochemically-generated cyclic enyne–allene

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Publication details

The article was received on 17 Jun 2009, accepted on 27 Jul 2009 and first published on 14 Aug 2009


Article type: Communication
DOI: 10.1039/B911871C
Chem. Commun., 2009, 5707-5709

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    Dual reactivity of a photochemically-generated cyclic enyne–allene

    A. V. Kuzmin and V. V. Popik, Chem. Commun., 2009, 5707
    DOI: 10.1039/B911871C

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