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Issue 44, 2009
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Expanding the scope of transformations of organoboron species: carbon–carbon bond formation with retention of configuration

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Abstract

The use of boron chemistry for the synthesis of enantiomerically enriched organic compounds is described. Key advances towards the preparation of organoboranes with control of stereochemistry are supplemented by a discussion of the use of these chiral organoboranes in carbon–carbon bond forming reactions. Particular emphasis is given to advances in the Suzuki–Miyaura coupling of chiral secondary organoboranes and homologation reactions. Both of these reactions convert the initially generated B–C bond into a C–C bond and thus lead to a significant increase in complexity.

Graphical abstract: Expanding the scope of transformations of organoboron species: carbon–carbon bond formation with retention of configuration

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Article information


Submitted
12 Jun 2009
Accepted
11 Aug 2009
First published
23 Sep 2009

Chem. Commun., 2009, 6704-6716
Article type
Feature Article

Expanding the scope of transformations of organoboron species: carbon–carbon bond formation with retention of configuration

C. M. Crudden, B. W. Glasspoole and C. J. Lata, Chem. Commun., 2009, 6704
DOI: 10.1039/B911537D

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